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A unified description of classical and quantal scattering

University of British Columbia

A unified description of classical and quantal scattering is presented. This description is unified both in the mathematical language and in the conceptual pictures that are used. Statistical states and observables, represented in phase space, are emphasized while both the time dependent trajectory and stationary state beam pictures are used. Semiclassical-type approximation schemes to the generalized differential cross section are presented for the single and double potential cases. Connection is made with the Born and distorted wave Born approximations, for both quantum and classical mechanics. A similar semiclassical-type approximation scheme for the double potential internal state kinetic cross section is presented. Connection is also made with the 'constant acceleration approximation' of Oppenheim and Bloom. Zwanzig's projection operator method is used to express the kinetic cross sections in terms of memory effects for the interacting observables.

Text

2010-03-02

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http://hdl.handle.net/2429/21309

Chemistry

University of British Columbia

Graduate