- Library Home /
- Search Collections /
- Open Collections /
- Browse Collections /
- UBC Theses and Dissertations /
- Preparation and properties of metal difluorophosphates
Open Collections
UBC Theses and Dissertations
UBC Theses and Dissertations
Preparation and properties of metal difluorophosphates Tan, Thiam Hock
Abstract
Twenty-seven difluorophosphates are successfully prepared by the displacement reactions of anhydrous chlorides or arylcarboxylates with purified difluorophosphoric acid. Vibrational spectra are obtained for these difluorophosphates and assignments made. The effects of cation-anion interactions on the vibrational frequencies of the PO₂F₂ group are also examined. Mossbauer parameters for five dialkyltin bis-difluorophosphates are reported and compared with those of analogous fluorosulfate derivatives. Electrical conductivity, nuclear magnetic resonance and density studies of solutions of some metal difluorophosphates in difluorophosphoric acid are made in an attempt to obtain a better understanding of solution behaviour in difluorophosphoric acid.
Item Metadata
Title |
Preparation and properties of metal difluorophosphates
|
Creator | |
Publisher |
University of British Columbia
|
Date Issued |
1970
|
Description |
Twenty-seven difluorophosphates are successfully prepared by the displacement reactions of anhydrous chlorides or arylcarboxylates with purified difluorophosphoric acid. Vibrational spectra are obtained for these difluorophosphates and assignments made. The effects of cation-anion interactions on the vibrational frequencies of the PO₂F₂ group are also examined. Mossbauer parameters for five dialkyltin bis-difluorophosphates are reported and compared with those of analogous fluorosulfate derivatives. Electrical conductivity, nuclear magnetic resonance and density studies of solutions of some metal difluorophosphates in difluorophosphoric acid are made in an attempt to obtain a better understanding of solution behaviour in difluorophosphoric acid.
|
Genre | |
Type | |
Language |
eng
|
Date Available |
2011-06-02
|
Provider |
Vancouver : University of British Columbia Library
|
Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
|
DOI |
10.14288/1.0059945
|
URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
|
Campus | |
Scholarly Level |
Graduate
|
Aggregated Source Repository |
DSpace
|
Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.