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Deuteron magnetic resonance properties in deuterated modifications of methane De Wit, Gerald Aloysius
Abstract
Relaxation properties of the deuteron spin system in CD₄ and CD₃H were studied in the temperature range from 105°K - 57°K. These results show that the intra-molecular quadrupole interactions dominate and the relaxation occurs through the molecular reorientations of the molecule. The deuteron spin-lattice relaxation times are approximately temperature independent, except for a small contribution from the magnetic dipolar interactions near the melting point in CD₃H. From this data it is concluded that the reorientatlonal correlation time is temperature independent. The deuteron T₂ shows the same temperature dependence as the proton T₂; the deuteron T₂ can be accounted for on the basis of magnetic dipolar interactions alone.
Item Metadata
Title |
Deuteron magnetic resonance properties in deuterated modifications of methane
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
1962
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Description |
Relaxation properties of the deuteron spin system in CD₄ and CD₃H were studied in the temperature range from 105°K - 57°K. These results show that the intra-molecular quadrupole interactions dominate and the relaxation occurs through the molecular reorientations of the molecule.
The deuteron spin-lattice relaxation times are approximately temperature independent, except for a small contribution from the magnetic dipolar interactions near the melting point in CD₃H. From this data it is concluded that the reorientatlonal correlation time is temperature independent.
The deuteron T₂ shows the same temperature dependence as the proton T₂; the deuteron T₂ can be accounted for on the basis of magnetic dipolar interactions alone.
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Genre | |
Type | |
Language |
eng
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Date Available |
2011-10-14
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Provider |
Vancouver : University of British Columbia Library
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Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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DOI |
10.14288/1.0085822
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Campus | |
Scholarly Level |
Graduate
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Aggregated Source Repository |
DSpace
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Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.