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UBC Theses and Dissertations
Synthesis and reactivity of macrocyclic β-keto lactones Sharadendu, Anurag
Abstract
As a part of a continuing study of the chemistry and conformational behaviour of macrocyclic β-keto lactones, 3-oxo-13-tetradecanolide (74) and 3-oxo-15-hexadecanolide (84) were synthesized via intra- and intermolecular alcoholysis of hydroxy Meldrum's acid derivatives. A number of 14- and 16-membered lactones, derived from 74 and 84 were used to investigate a series of alkylation and reduction reactions. [more abstract available in pdf]
Item Metadata
| Title |
Synthesis and reactivity of macrocyclic β-keto lactones
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| Creator | |
| Publisher |
University of British Columbia
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| Date Issued |
1996
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| Description |
As a part of a continuing study of the chemistry and conformational behaviour of
macrocyclic β-keto lactones, 3-oxo-13-tetradecanolide (74) and 3-oxo-15-hexadecanolide (84) were synthesized via intra- and intermolecular
alcoholysis of hydroxy Meldrum's acid derivatives. A number of 14- and
16-membered lactones, derived from 74 and 84 were used to investigate a
series of alkylation and reduction reactions.
[more abstract available in pdf]
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| Extent |
7314188 bytes
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| Genre | |
| Type | |
| File Format |
application/pdf
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| Language |
eng
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| Date Available |
2009-02-18
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| Provider |
Vancouver : University of British Columbia Library
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| Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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| DOI |
10.14288/1.0059553
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| URI | |
| Degree | |
| Program | |
| Affiliation | |
| Degree Grantor |
University of British Columbia
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| Graduation Date |
1996-05
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| Campus | |
| Scholarly Level |
Graduate
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| Aggregated Source Repository |
DSpace
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Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.