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UBC Theses and Dissertations
Solution H₂S Chemistry of Pd-bis(Diphenylphosphino)methane (DPM) complexes; catalytic conversion of H₂S to H₂ Wong, Terrance Yu Hung
Abstract
This thesis describes studies on the interaction of H₂S with mono- and dinuclear Pd - dpm (bis(diphenylphosphino)methane) complexes with the ultimate goal being to catalyze the conversion of H₂S to H₂ and elemental sulfur (S₈). Solution kinetic and mechanistic studies were performed on the abstraction of sulfur from Pd₂X₂(µ-S)(µ-dpm)₂ [X = Cl (2a), Br (2b), I (2c)] using dpm to give, respectively, Pd₂X₂(dpm)₂ [X = Cl (1a), Br (1b), I (1c)] and dpm(S) (process 2 → 1): [More abstract follows which cannot be rendered here; please see pp.3+ of the accompanying pdf file].
Item Metadata
Title |
Solution H₂S Chemistry of Pd-bis(Diphenylphosphino)methane (DPM) complexes; catalytic conversion of H₂S to H₂
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Creator | |
Publisher |
University of British Columbia
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Date Issued |
1996
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Description |
This thesis describes studies on the interaction of H₂S with mono- and dinuclear Pd - dpm
(bis(diphenylphosphino)methane) complexes with the ultimate goal being to catalyze the
conversion of H₂S to H₂ and elemental sulfur (S₈).
Solution kinetic and mechanistic studies were performed on the abstraction of sulfur from
Pd₂X₂(µ-S)(µ-dpm)₂ [X = Cl (2a), Br (2b), I (2c)] using dpm to give, respectively, Pd₂X₂(dpm)₂
[X = Cl (1a), Br (1b), I (1c)] and dpm(S) (process 2 → 1):
[More abstract follows which cannot be rendered here; please see pp.3+ of the accompanying pdf file].
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Extent |
11328762 bytes
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Genre | |
Type | |
File Format |
application/pdf
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Language |
eng
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Date Available |
2009-03-17
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Provider |
Vancouver : University of British Columbia Library
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Rights |
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.
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DOI |
10.14288/1.0059521
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URI | |
Degree | |
Program | |
Affiliation | |
Degree Grantor |
University of British Columbia
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Graduation Date |
1996-11
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Campus | |
Scholarly Level |
Graduate
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Aggregated Source Repository |
DSpace
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Item Media
Item Citations and Data
Rights
For non-commercial purposes only, such as research, private study and education. Additional conditions apply, see Terms of Use https://open.library.ubc.ca/terms_of_use.